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孙键

 




                      孙 键(Jian Sun),硕士生导师   

                       电子邮箱: sunj2077@ahnu.edu.cn

                       ORCID: 0000-0001-9397-3191

                        

 




个人经历

2008.09-2012.07      华东理工大学(ECUST),学士

2012.09-2018.01     中国科学院上海有机化学研究所(SIOC),理学博士(导师:邓亮 研究员)

2018.04-2021.11      德国哥廷根大学,博士后(导师:Sven Schneider 教授)

2022.06 至今          安徽师范大学(AHNU


研究兴趣

金属有机化学



代表性论文

1.  Sun, J.; Ou, C.; Wang, C.*; Uchiyama, M.; Deng, L.Silane-Functionalized N-Heterocyclic Carbene–Cobalt Complexes 

     Containing a Five-Coordinate Silicon with a Covalent Co–Si Bond, Organometallics 2015, 34, 1546-1551.

2.  Sun, J.; Deng, L.* Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and AlkynesACS Catal. 2016, 6, 290–300.

3.  Sun, J.; Luo, L.; Luo, Y.; Deng, L.* An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition of C-H, N-H, and O-H 

     Bonds to Cobalt(I) Complexes. Angew. Chem., Int. Ed2017, 562720–2724.

4.  Sun, J.; Gao, Y.; Deng, L.*Low-Coordinate NHC-Cobalt(0)-Olefin Complexes: Synthesis, Structure, and Their Reactions 

     with Hydrosilanes. Inorg. Chem. 201756, 10775-10784.

5.  Sun, J.; Abbenseth, J.; Verplancke, H.; Diefenbach, M.; de Bruin, B.; Hunger, D.; Würtele, C.; van Slageren, J.; 

     Holthausen, M. C.; Schneider, SA Platinum Metallonitrene with a Triplet Ground State. Nat. Chem. 2020, 12, 1054–1059.

6.  Sun, J.;# Verplancke, H.;# Schweizer, J. I.; Diefenbach, M.; Würtele, C.; Otte, M.; Tkach, I.; Herwig, C.; Limberg, C.; 

     Demeshko, S.; Holthausen, M. C.*; Schneider, S.* Stabilizing P≡P: P22–, P2⋅–, and P20 as bridging ligands. Chem 20217, 

     1952-1962(# contributed equally to this work)

7.  Bai, W.; Sun, J.; Wang, D.*; Bai, S.*; Deng, L.* Low-Coordinate Cobalt(0) N-Heterocyclic Carbene Complexes as Catalysts

     for Hydrosilylation of Alkynes. Appl. Organomet. Chem. 2022, 36, e6694.

     


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