陈郑   副教授  硕士生导师 博士生导师   (招生专业：化学工程与技术、无机化学)

实验室：礼勤楼724-725

办公室：礼勤楼740 

邮箱：chenzh07@mail.ahnu.edu.cn

教育经历

博士：化学 (2014 年 9 月-2017 年 7 月)     清华大学               导师：李亚栋 院士

硕士：有机化学 (2010 年 9 月-2013 年 7 月)        安徽师范大学       导师：王绍武 教授 

本科：材料化学 (2006 年 9 月-2010 年 7 月)        安徽师范大学    导师：郝二宏 教授  

工作经历

2022年12月-至今     安徽师范大学78mppt威九国际 副教授

2019年7月-2022年11月 安徽师范大学78mppt威九国际 讲师    

2017年7月-2019年7月  清华大学化学系   物理学博士后

2013年7月-2014年9月 清华大学化学系研究助理

主持项目：

1.“单原子位点金催化Si-H键活化反应研究”，国家自然科学基金青年项目，2020年1月至 2022年 12月，项目负责人（21901007）

2.“面向CO₂化工利用生产碳酸乙烯酯的催化材料开发”，安徽省重点研究与开发计划项目，2022年1月至2024年12月，项目负责人（2022a05020048）

3.“钴基纳米催化材料的精准合成及在烃类氧化反应中的性能研究”，安徽省自然科学基金青年项目，2020年7月至2022年6月，项目负责人（2008085QB83）

4.“单原子催化材料在氧化反应中的应用”，安徽师范大学人才科研启动费，2019年9月至2021年9月，项目负责人

5.“单原子催化材料应用于C-H键选择性催化氧化研究”，安徽省高校优秀拔尖人才培育重点项目，2022年3月至2024年2月，项目负责人（gxyqZD2022012）

6.“清洁能源转化材料的开发和应用”，环境污染物降解与监测安徽省重点实验室开放课题，2022年6月至2024年5月，项目负责人（FSKFKT007D）

7.“配位聚合物衍生的单原子催化剂研制”，配位化学国家重点实验室开放课题，2023年2月至2025年1月，项目负责人（SKLCC2307）

8.“基于原油馏分中烃类催化氧化的3d后过渡金属单原子催化剂研制”，重质油全国重点实验室开放课题，2023年6月至2025年5月，项目负责人（SKLHOP202202007）

9.“基于氢能开发和利用的Ru基团簇材料研制”，先进能源材料化学教育部重点实验室，2024年01月至2025年12月，项目负责人

10.“单原子催化精细化学品合成”，安徽省高校优秀青年科研项目，2023年9月至2026年8月，项目负责人（2023AH030050）

11.“多级位点复合构筑燃料电池低Pt催化剂及膜电极性能研究”，安徽省高校协同创新项目，2024年1月1日至2025年12月31日，项目负责人（GXXT-2023-034）

研究领域：

1. 纳米催化  

2. 金属参与的有机反应 

3. 氢能源开发与利用

讲授课程：

工业催化原理

能源科学导论

应用化学专业实验（食品抗氧化剂的制备）

精细化工实训(洗衣液工艺与制备)

课题组成员：

2024级博士生：周炎

2022级博士生：吕闪闪

2024级硕士生：夏昕、谢琴琴、章志翔（陈硕联合培养）

2023级硕士生：钱昌进、汪晓琪、赵国志（赵国锋联合培养）

2022级硕士生：宋缦缦、李峰、冯萌萌

发表论文：

2024

Yan Zhou, Shanshan Lv, Mengmeng Feng, Changjin Qian, Shoujie Liu*, and Zheng Chen*, Ligand-assisted formation of mesoporous Zn-N-C to realize superior catalytic activity in solvent-free CO₂ cycloaddition reactions. Chemical Communications, 2024, 60(19), 2641-2644.

Guozhi Wu, Shanqing Li, Zheng Chen*, Ajiao Sun, Jie Yang, Sang Woo Joo, and Jiarui Huang*, MoP nanoparticles encapsulated in N-doped carbon nanotubes as sulfur host for advanced lithium-sulfur batteries. Nano Research, 2024, 17(4), 2736-2745.

Biao Wei, Chaoqun Wang, Hui Miao*, Zhibiao Qin, Mengna Huang, Yan Xu, Wenhui Xue, Shucheng Yang, Chenxu Liu, Cuibing Bai, and Zheng Chen*, Novel bidentate N-coordinated alkylaluminum complexes: synthesis, characterization, and efficient catalysis for hydrophosphonylation. Dalton Transactions, 2024, 53(9), 4185-4193.

Chaoqun Wang, Mengna Huang, Hui Miao*, Chenxu Liu, Zhibiao Qin, Wenning Ma, Mengmeng Han, Junjie Yu, Yongmin Li, Biao Wei*, and Zheng Chen*, Alkylaluminum Complexes Featuring Bridged Bis-Formylfluorenimide Ligands for Hydroboration of Aldehyde, Ketone, and Imines. Inorganic Chemistry, 2024, 63(41), 19332-19343.

Manman Song, Mengmeng Feng, Feng Li, Shanshan Lv, Yan Zhou, and Zheng Chen*, Electrosynthesis of Amides through Cu- and Co-Incorporated Nickel Hydroxide-Catalyzed Oxidation of Primary Amines Coupled with Hydrogen Evolution. Inorganic Chemistry, 2024, 63(32), 15215-15223.

Feng Li, Qikang Wu*, Wenjuan Yuan*, and Zheng Chen*, Ruthenium-based single atom catalysts: synthesis and application in the electrocatalytic hydrogen evolution reaction. Dalton Transactions, 2024, 53(29), 12022-12033.

Ke Cao, Yan Zhou, Shanshan Lv, Mengmeng Feng, Changjin Qian, and Zheng Chen, Cobalt-manganese bimetallic organic frameworks catalyzed solvent-free oxidation of benzyl C-H bonds with O₂ as sole oxidant. Nano Research, 2024, doi: 10.1007/s12274-024-6944-3.

2023

Qikang Wu, Wenjuan Yang*, Xingdong Wang, Wei Zhu*, Shanshan Lv, Yan Zhou, Taiyu Chen, Shaohuan Liu, Wanying Li, Zheng Chen*. Inherent vacancy of compressive Ru nanoparticles accelerate electro-catalytic hydrogen energy conversion. Applied Catalysis B: Environmental, 2023, 335, 122896.

Yiming Zhao,Yan Zhou,Shanshan Lv,Han Li,Qikang Wu,Shaohuan Liu,Wanying Li,Taiyu Chen and Zheng Chen*, Single Atom Copper Catalyst for S-arylation Reaction to Produce Diaryl Disulfides. Chemical Science, 2023,  14(17), 4620-4626.

Qikang Wu, Xiaobo Yang, Jing Yang, Pengfei Liu, Guixiang Ding, Zheng Chen*, Guangfu Liao*. Size effect of ruthenium nanoparticles on water cracking properties with different crystal planes for boosting electrocatalytic hydrogen evolution. Journal of Colloid and Interface Science, 2023, 644, 238-245.

Jiali Ren⁺, Yan Zhou⁺, Hui Miao*, Chaoqun Wang, Shanshan Lv, Manman Song, Feng Li, Mengmeng Feng, Zheng Chen*, Solvent-free oxidation of benzyl C–H to ketone with Co–Ni layered double hydroxide as the catalyst and O₂ as the sole oxidant. Dalton Transactions, 2023, 52(19), 6398-6406.

Ruirui Yun*, Ruiming Xu, Changsong Shi, Beibei Zhang, Tuanhui Li, Lei He, Tian Sheng*, and Zheng Chen*, Post-modification of MOF to Fabricate Single-atom Dispersed Hollow Nanocages Catalysts for Enhancing CO₂ Conversion. Nano Research, 2023, 16(7), 8970-8976. 

Taiyu Chen, Qikang Wu, Feng Li, Rui Zhong, and Zheng Chen, Co₂P-Ni₃S₂ Heterostructured Nanocrystals as Catalysts for Urea Electrooxidation and Urea-Assisted Water Splitting. ACS Applied Nano Materials, 2023. 6(19), 18364-18371. 

2022

Yan Zhou, Shanshan Lv, Han Li, Qikang Wu, Taiyu Chen, Shaohuan Liu, Wanying Li, Wenjuan Yang*, Zheng Chen*, MIL-47(V)-Derived Carbon-doped Vanadium Oxide for Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran. Dalton Transactions, 2022, 51(48): 18473-18479.

Han Li, Shanshan Lv, Yan Zhou, Qikang Wu, Shaohuan Liu, Taiyu Chen, Wanying Li, Zheng Chen*. Mesoporous Nitrogen-Doped Graphitized Carbon for Recyclable Oxidation of Cyclohexene. ACS Applied Nano Materials, 2022, 5(8): 11723-11730.

Qikang Wu, Han Li, Yan Zhou, Shanshan Lv, Taiyu Chen, Shaohuan Liu, Wanying Li, and Zheng Chen*, Convenient Synthesis of a Ru Catalyst Containing Single Atoms and Nanoparticles on Nitrogen-Doped Carbon with Superior Hydrogen Evolution Reaction Activity in a Wide pH Range, Inorganic Chemistry, 2022, 61(28): 11011-11021.

Ruirui Yun,* Tuanhui Li, Beibei Zhang, Lei He, Shoujie Liu, Can Yu,* Zheng Chen,* and Shizhong Luo, Amino Induced High-Loading Atomically Dispersed Co sites on N-doped Hollow Carbon for Efficient CO₂ Transformation, Chemical Communications, 2022, 58(46): 6602-6605.

Muhammad Mateen*, Ling Gao, Muhammad Nadeem Akhtar, Weng-Chon CHEONG (Max)*, Shanshan Lv, Yan Zhou, Zheng Chen*, Engineering electrophilic atomic Ir sites on CeO₂ colloidal spheres for selectivity control in hydrogenation of α,β-unsaturated carbonyl compounds. Nano Research, 2022, 15(8): 7107-7115.

Tao Wu, Sha Li, Shoujie Liu, Weng-Chon Cheong, Cheng Peng, Kai Yao, Yingping Li, Jieyue Wang, Binbin Jiang*, Zheng Chen*, Zhiming Chen, Xianwen Wei and Konglin Wu*, Biomass-assisted approach for large-scale construction of multi-functional isolated single-atom site catalysts, Nano Research, 2022, 15(5): 3980-3990.

Songrui Wang⁺, Minmin Wang⁺, Zhi Liu⁺, Shoujie Liu, Yanju Chen, Min Li, Hui Zhang, Qikang Wu, Jiahui Guo, Xueqing Feng, Zheng Chen* and Yuan Pan*, Synergetic Function of the Single-Atom Ru-N₄ Site and Ru Nanoparticles for Hydrogen Production in a Wide pH Range and Seawater Electrolysis, ACS Applied Materials & Interfaces, 2022, 14(13): 15250-15258.

Qikang Wu, Songrui Wang, Jiahui Guo, Xueqing Feng, Han Li, Shanshan Lv, Yan Zhou, and Zheng Chen*, Insight into sulfur and iron effect of binary nickel-iron sulfide on oxygen evolution reaction, Nano Research, 2022, 15(3): 1901-1908.

Jianbo Zhao*, Haifeng Yuan, Guang Yang, Yingfan Liu, Xiaomei Qin, Zheng Chen*, Cheong Weng-Chon, Liming Zhou, Shaoming Fang*, AuPt bimetallic nanoalloys supported on SBA-15: A superior catalyst for quinoline selective hydrogenation in water, Nano Research, 2022, 15(3): 1796-1802.

2021

Jiahui Guo, Xueqing Feng, Songrui Wang, Qikang Wu, Shanshan Lv, Yan Zhou,Han Li, Zheng Chen* and Yuzhong Zhang*, Facile synthesis of hexagonal a-Co(OH)₂ nanosheets and their superior activity in the selective reduction of nitro compounds, Dalton Transactions, 2021, 50(48): 18061-18068.
Wuzhengzhi Zhang, Lianchun Ding, Weipei Sun, Zhengcui Wu*, Zheng Chen*,and Feng Gao*, Br-Doped CuO Multilamellar Mesoporous Nanosheets with Oxygen Vacancies and Cetyltrimethyl Ammonium Cations Adsorption for Optimizing Intermediate Species and Their Adsorption Behaviors toward CO₂ Electroreduction to Ethanol with a High Faradaic Efficiency, Inorganic Chemistry, 2021, 60(18): 14371-14381.
Xueqing Feng, Jiahui Guo, Songrui Wang, Qikang Wu and Zheng Chen*,  Atomically Dispersed Gold Anchored on Carbon Nitride Nanosheets as Effective Catalyst for Regioselective Hydrosilylation of Alkynes, Journal of Materials Chemistry A, 2021, 9(33): 17885-17892. 
Chenchen Qiang, Min Liu, Liang Zhang, Zheng Chen*, and Zhen Fang*, In Situ Growth of Ni-Based Metal–Organic Framework Nanosheets on Carbon Nanotube Films for Efficient Oxygen Evolution Reaction,  Inorganic Chemistry,  2021, 60(5): 3439-3446.

Qikang Wu, Yuqin Zhu, Jiahui Guo, Songrui Wang, Xueqing Feng, Zheng Chen*, Insight into the influence of doped oxygen on active sites of molybdenum sulfide materials in hydrogen evolution reaction, International Journal of Hydrogen Energy, 2021, 46(21): 11721-11730.

Xiao Han^#, Zheng Chen^#, Wenxing Chen^#, Chunlin Lv, Yongjun Ji, Jing Li, Weng-Chon Cheong, Xiaojuan Lei, Qing Peng, Chen Chen, Dingsheng Wang, Chao Lian,* and Yadong Li, A General Strategy to Prepare Atomically Dispersed Biomimetic Catalysts Based on Host-guest Chemistry, Chemical Communications, 2021, 57(15), 1895-1898.

Konglin Wu, Min Ling, Peiyuan Zeng, Liang Zhang, Tao Wu, Pingli Guan, Weng-Chon Cheong, Zheng Chen*, Zhen Fang, Xianwen Wei*, Multifunctional self-assembly Fe₃O₄ hierarchical microspheres: high-efficiency lithium ion battery materials and hydrogenation catalysts, Science China Materials, 2021, 64(5): 1058-1070.

2020

Ruoyun Dai, Weng‐Chon Cheong, Jiqing Jiao, Chao Zhang, Yu Zhang, Zheng Chen*, Caiyun Nan, Chen Chen*, Optimized Self‐Templating Synthesis Method for Highly Crystalline Hollow Cu₂O Nanoboxes, Small Methods, 2020, 4(12): 2000521.

Zheng Chen*, Wenjuan Yang^#, Yue Wu, Chao Zhang, Jun Luo, Chen Chen, and Yadong Li, Atomic iron on mesoporous N-doped carbon to achieve dehydrogenation reaction at room temperature, Nano Research, 2020, 13(11): 3075-3081.

Konglin Wu, Fei Zhan, Renyong Tu, Weng-Chon Cheong,  Yuansheng Cheng, Lirong Zheng,  Wensheng Yan,  Qinghua Zhang,  Zheng Chen* and  Chen Chen*, Dopamine polymer derived isolated single-atom site metals/N-doped porous carbon for benzene oxidation, Chemical Communications, 2020, 56(63): 8916-8919.

Zheng Chen^#, Yinjuan Chen^#, Songlin Chao^#, Xiaobin Dong, Wenxing Chen, Jun Luo, Chenguang Liu, Dingsheng Wang, Chen Chen, Wei Li*, Jun Li*, and Yadong Li*, Single Atom Au^I-N₃ Site for Acetylene Hydrochlorination Reaction, ACS Catalysis, 2020, 10(3): 1865-1870.

Zewen Zhuang^#, Yu Wang^#, Zheng Chen^#, Dingsheng Wang,Chen Chen,* Qing Peng*  and  Yadong Li*, MOF derived high-density atomic platinum heterogeneous catalyst for C-H bond activation, Materials Chemistry Frontiers, 2020, 4(4): 1158-1163.

会议论文：

铜族元素单原子催化剂在碳-杂原子键构筑反应中的应用，陈郑，中国化学会第33届学术年会，山东省青岛市，2023-06-17，口头报告。

IB族金属单原子催化剂在杂原子化合物绿色合成反应中的应用，陈郑，中国化学会首届全国绿色化学学术会议，浙江省新昌县，2023-04-21，口头报告。

应用于乙炔氢氯化反应的单原子位点金属催化材料设计合成，陈郑，长三角一体化暨安徽省第一届催化学术会议，安徽省淮北市，2021-05-28，邀请报告。

稀土胺基化合物与Schiff碱型8-羟基喹啉衍生物反应性能研究，陈郑、苗慧、杨松、周双六、王绍武，第十七届全国金属有机化学学术讨论会，2012-10-19，墙报。

授权专利：

陈郑；李亚栋，一种利用三聚氰胺甲醛树脂制备金属单原子材料的方法、金属单原子材料及其应用，专利号：ZL 202010389145.0

陈郑；周炎，一种钴锰双金属有机框架材料及其制备方法和在乙苯C-H键选择性氧化反应中的应用，专利号：ZL 202210549580.4