周双六
周双六 教授 博士生导师
E-mail：slzhou@ahnu.edu.cn
电话：0553-3937138
ORCID: http://orcid.org/0000-0002-0103-294X
所受教育：
· 学士（1991-1995）安徽工程大学
· 硕士（2000-2003）安徽师范大学
· 博士（2004-2007）安徽师范大学
职称职位：
· 2003年－现在 安徽师范大学讲师，副教授，教授（2012年）
· 2007年－2009年 台湾中兴大学化学系博士后研究员
· 2008年11月－现在 安徽师范大学硕士生导师
· 2017年12月－现在 安徽师范大学博士生导师
主持项目：
1. 含氮、氧原子侧链吡咯基多齿配体稀土金属配合物的合成及其反应性研究，国家自然科学基金(21672004)，2017-2020，项目主持人。
2. 新型手性稀土金属胺基配合物的合成及其催化碳-磷键选择性形成反应研究，国家自然科学基金(21372009)，2014-2017，项目主持人，已结题。
3. 手性稀土金属配合物催化芳香基（或杂芳香基）铝试剂对醛酮的不对称加成反应研究，国家自然科学基金(21172003)，2012-2015，项目主持人，已结题。
4. 单磺酰基联萘酚基锌镁铝金属配合物催化丙交酯开环聚合反应研究，安徽省自然科学基金(11040606M36)，2011-2013，项目主持人，已结题。
5. 外消旋稀土金属有机配合物的控制性合成及其催化烯烃可控聚合研究，国家自然科学基金(21802001)，2009-2011，项目主持人，已结题。
6. 氮原子配位促进稀土金属-氮键均裂反应研究，安徽省高校青年教师资助计划（2004jq120），项目主持人，已结题。
研究领域：
1. 金属有机化学
2. 不对称催化合成
讲授课程：
1. 化工基础
2. 应用有机合成
3. 化学文献检索与利用
4. 工程制图
5. 应化专业实验
代表性论文:
30. Jiayu Yan, Shuangliu Zhou,* Yukun Wei, Qian Liu, Donghan Wang, Lijun Zhang, Qingbing Yuan, Shaowu Wang,* Ether/Thioether Functionalized Dianionic α-Iminopyridine Rare-Earth Metal Amido Complexes and Their Catalytic Activities toward Hydrophosphination of Alkenes, Organometallics 2023, 42, 81-90.
29. Jianan Yang, Jianan Yang, Yingjie Ma, Qing Liu, Xuebing Leng, Shuangliu Zhou*, Shengfa Ye, Liang Deng*, Shaowu Wang,* Noninnocent Behavior of a (3-Imino)indol-2-yl Ligand in Metal Complexes, Organometallics 2022, 41, 480-485.
28. Xiuli Zhang, Shuangliu Zhou,* Donghan Wang, Lijun Zhang, Yun Wei, Xiancui Zhu, Peng Cui, Gen Luo,* Shaowu Wang,* Syntheses of Rare-Earth Metal Alkyl Complexes Bearing a Dianionic a-Iminopyridyl Ligand and Their Catalytic Activities toward Polymerization of 2-Vinylpyridine, Organometallics 2021, 40, 3462-3471.
27. Weiming Sheng, Xiaolong Xu, Shuangliu Zhou,* Xiuli Zhang, Zeming Huang, Jun Du, Lijun Zhang, Yun Wei, Xiancui Zhu, Peng Cui, Shaowu Wang,* Synthesis and Reactivity of NNNNN-Pincer Multidentate Pyrrolyl Rare-Earth-Metal Amido-Chloride or Dialkyl Complexes, Organometallics 2020, 39, 4525-4534.
26. Xiuli Zhang, Shuangliu Zhou,* Xiaofei Fang, Lijun Zhang, Guide Tao, Yun Wei, Xiancui Zhu, Peng Cui, Shaowu Wang,* Syntheses of Dianionic a-Iminopyridine Rare-earth Metal Complexes and Their Catalytic Acitivities toward Dehydrogenative Coupling of Amines with Hydrosilanes, Inorg. Chem. 2020, 59, 9683-9692.
25. Wei Wang, Xiaojia Wang, Shuangliu Zhou,* Xiaolong Xu, Jun Du, Lijun Zhang, Xiaolong Mu, Yun Wei, Xiancui Zhu, and Shaowu Wang,* Syntheses, Structures, and Catalytic Activities of the Anionic Heterobimetallic Rare-Earth Metal Complexes Supported by Pyrrolyl-Substituted 1,2-Diimino Ligands, Inorg. Chem. 2018, 57, 10390-10400.
24. Hong Fang, Zhiyong Yang, Lijun Zhang, Wei Wang, Yimei Li, Xiaolong Xu, and Shuangliu Zhou,* Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents, Org. Lett. 2016, 18, 6022-6025.
23. Shuangliu Zhou,* Zhiyong Yang, Xu Chen, Yimei Li, Lijun Zhang, Hong Fang, Wei Wang, Xiancui Zhu, Shaowu Wang,* Copper-Catalyzed Electrophilic Amination of Organoaluminum Nucleophiles with O-Benzoyl Hydroxylamines, J. Org. Chem. 2015, 80, 6323-6228.
22. Lijun Zhang,* Bing Tu, Min Ge, Yimei Li, Liangyu Chen, Wei Wang, and Shuangliu Zhou,* Asymmetric Addition of Pyridyl Aluminum Reagents to Aldehydes Catalyzed by a Titanium(IV) Catalytic System of (R)-H8-BINOLate, J. Org. Chem. 2015, 80, 8307-8313.
21. Hui Miao, Fenhua Wang, Shuangliu Zhou,* Guangchao Zhang, Yang Li, Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen, Org. Biomol. Chem., 2015, 13, 4647-4651.
20. Liping Guo, Xiancui Zhu, Guangchao Zhang, Yun Wei, Lixin Ning, Shuangliu Zhou,* Zhijun Feng, Shaowu Wang,* Xiaolong Mu, Jun Chen, Synthesis and Characterization of Organo-Rare-Earth Metal Monoalkyl Complexes Supported by Carbon σ-Bonded Indolyl Ligands: High Specific Isoprene 1,4-Cis Polymerization Catalysts, Inorg. Chem. 2015, 54, 5725-5731.
19.Yun Wei, Shaowu Wang,* Shuangliu Zhou,* Zhijun Feng, Liping Guo, Xiancui Zhu, Xiaolong Mu, Fangshi Yao, Aluminum Alkyl Complexes Supported by Bidentate N,N-Ligands: Synthesis, Structure, and Catalytic Activity for Guanylation of Amines, Organometallics 2015, 34, 1882-1889.
18. Qingbing Yuan, Shuangliu Zhou,* Xiancui Zhu, Yun Wei, Shaowu Wang,* Xiaolong Mu, Fangshi Yao, Guangchao Zhang and Zheng Chen, Heterometallic rare-earth metal complexes with imino-functionalized 8-hydroxyquinolyl ligands: synthesis, characterization and catalytic activity towards hydrophosphinylation of trans-β-nitroalkene, New J. Chem. 2015, 39, 7626-7632.
17. Xu Chen, Lingmin Zhou, Yimei Li, Tao Xie, Shuangliu Zhou*, Synthesis of Heteroaryl Compounds through Cross-Coupling Reaction of Aryl Bromides or Benzyl Halides with Thienyl and Pyridyl Aluminum Reagents, J. Org. Chem. 2014, 79, 230-239.
16. Liping Guo, Xiancui Zhu, Shuangliu Zhou,* Xiaolong Mu, Yun Wei, Shaowu Wang,* Zhijun Feng, Guangchao Zhang, Baojia Deng, Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization, Dalton Trans. 2014, 43, 6842-6847.
15. Shuangliu Zhou,* Zhangshuan Wu, Lingmin Zhou, Shaowu Wang,* Lijun Zhang, Xiancui Zhu, Yun Wei, Jinhua Zhai, and Jie Wu, Controlled Synthesis of Racemic Indenyl Rare-Earth Metal Complexes via the Cooperation between the Intramolecular Coordination of Donor Atoms and a Bridge, Inorg. Chem. 2013, 52, 6417-6426.
14. Qinghai Li, Shuangliu Zhou,* Shaowu Wang,* Xiancui Zhu, Lijun Zhang, Zhijun Feng, Liping Guo, Fenhua Wang and Yun Wei, Dehydrogenation of secondary amines: synthesis, and characterization of rare-earth metal complexes incorporating imino- or amido-functionalized pyrrolyl ligands, Dalton Trans. 2013, 42, 2861-2869.
13. Shuangliu Zhou, Zhangshuan Wu, Jiewei Rong, Shaowu Wang,* Gaosheng Yang, Xiancui Zhu, Lijun Zhang, Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes, Chem. Eur. J. 2012, 18, 2653-2659.
12. Shuangliu Zhou, Hengyu Wang,Jian Ping, Shaowu Wang,* Lijun Zhang,* Xiancui Zhu, Yun Wei, Fenhua Wang, Zhijun Feng, Xiaoxia Gu, Song Yang, and Hui Miao, Synthesis, Characterization of Organolanthanide Complexes with Calix[4]-pyrrolyl Ligand and Their Catalytic Activities towards Hydrophosphonylation of Aldehydes and Unactivated Ketones, Organometallics 2012, 31, 1696-1702.
11. Shuangliu Zhou,* Yongyao Jiang, Tao Xie, Zhanshuan Wu, Linmin Zhou, Wenjing Xu, Lijun Zhang, Shaowu Wang*, Synthesis, Structure of Zinc Complexes Containing Sulfonylated Binaphtholate Ligands and Their Catalytic Activities towards Ring-Opening Polymerization of Lactide and ε-Caprolactone, Chin. J. Chem. 2012, 30, 2176-2182.
10. Shuangliu Zhou, Chengwei Yin, Hui Wang, Xiancui Zhu, Gaosheng Yang, Shaowu Wang*, Synthesis, characterization, and catalytic activities of rare-earth metal complexes with iminopyrrolyl ligands, Inorg. Chem. Commun. 2011, 14, 1194-1120.
9. Shuangliu Zhou, Shihong Wu, Hong Zhu, Shaowu Wang,* Xiancui Zhu, Lijun Zhang, Gaosheng Yang, Daohui Cui, Hengyu Wang, Synthesis, structure and catalytic activity of alkali metal-free bent-sandwiched lanthanide amido complexes with calix[4]-pyrrolyl ligands, Dalton Trans. 2011, 40, 9447-9453.
8. Shuangliu Zhou, Chi-Ren Chen, Han-Mou Gau*, Highly Enantioselective 3-Furylation of Ketones Using (3-Furyl)titaniumNucleophile, Org. Lett. 2010, 12, 48-51.
7. Chao Liu, Shuangliu Zhou,* Shaowu Wang,* Lijun Zhang, Gaosheng Yang, Rare earth metal bis(trimethylsilyl)amido complexes bearing pyrrolyl-methylamide ligand. Synthesis, structure, and catalytic activity towards guanylation of amines, Dalton Trans. 2010, 39, 8994-8999.
6. Shuangliu Zhou, Kuo-Hui Wu, Chien-An Chen, Han-Mou Gau,* Highly Enantioselective Arylation of Aldehydes and Ketones Using AlArEt2(THF) as Aryl Sources, J. Org. Chem. 2009,74, 3500-3505.
5. Shuangliu Zhou, Da-Wei Chuang, Shih-Ju Chang, Han-Mou Gau,* Synthesis, Characterization, and Structures of Arylaluminum Reagents and Asymmetric Arylation of Aldehydes Catalyzed by a Titanium Complex ofN-Sulfonylated Amino Alcohol, Tetrahedron: Asymmetry 2009, 20, 1407-1412.
4. Shuangliu Zhou, Shaowu Wang,* Gaosheng Yang, Qinghai Li, Lijun Zhang, Zijian Yao, Zhangkai Zhou, and Haibin Song, Synthesis, Structure and Diverse Catalytic Activities of Ethylenebis(indenyl)lanthanide(III) Amides on the N-H, C-H Addition to Carbodiimides and ε-Caprolactone Polymerization, Organometallics 2007, 26, 3755-3761.
3. Shuangliu Zhou, Shaowu Wang,* Enhong Sheng, Lijun Zhang, Zeyan Yu, Xiaobing Xi, Guodong Chen, Wei Luo, and Yan Li, Synthesis, Characterization and Catalytic Activity of Some Neodymium(III) and Ytterbium(II) and Europium(II) Complexes With Pyrrolidinyl- and Piperidinyl-Functionalized Indenyl Ligands, Eur. J. Inorg. Chem. 2007, 1519-1528.
2. Shaowu Wang,* Shuangliu Zhou, Enhong Sheng, Meihua Xie, Kehua Zhang,Lin Cheng, Yan Feng, Lili Mao, and Zixiang Huang, Homolysis of the Eu-N Bond. Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes, Organometallics 2003, 22, 3546-3552.
1. Shuangliu Zhou, Shaowu Wang,* Gaosheng Yang, Xinyuan Liu, Enhong Sheng, Kehua Zhang, Lin Cheng, Zixiang Huang, Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln(m-Cl)Li(THF)3 (Ln = Nd, Sm, Eu), Polyhedron 2003, 22, 1019-1024.
会议论文及报告
1. 周双六，“新型双阴离子型α-吡啶亚胺基稀土金属有机配合物”，第二十一届全国金属有机化学学术研讨会。2022年8月，芜湖，报告。
2. 周双六，“有机铝试剂在有机合成中的应用”，第十四届江淮有机论坛。2016年11月，徐州，报告。
3. Hong Fang, Xiaolong Xu, Yangyang Jiang, Xiaojia Wang, Shuangliu Zhou*, “Organoaluminum Reagents’ Application on Asymmetric Cross-coupling Reaction”, 第九届全国金属有机化学学术会议。2015年8月，兰州，墙报。
4. 姜永要，周双六*，周凌敏，吴章栓，王绍武*，“磺酰基取代联萘酚锌配合物的合成、结构及其催化性质”，第七届全国有机化学学术讨论会。2011年11月，南京，墙报。
5. 吴章栓，周双六*，周凌敏，姜永要，王绍武*，“稀土胺基化合物催化a,b-不饱和羰基化合物的氢膦化反应”，第七届全国有机化学学术讨论会。2011年11月，南京，墙报。
6. Shuangliu Zhou and Han-Mou Gau*, “Application of the Aluminum Reagents in Enantioselective Arylation of Aldehydes”, 第五届海峡两岸生物无机与材料研讨会。2008年7月，台南，墙报。