朱先翠（教授，博士生导师）  E-mail: zxc0805@ahnu.edu.cn  花津校区实训大楼1105-1106室

  所受教育

• 博士（2012年）      安徽师范大学 

• 硕士（2008年）      安徽师范大学 

• 学士（1998年）      安徽大学 

 职称职位 

• 1998年-现在    助教，讲师，副教授，教授 

• 2013年       硕士生导师

• 2022年       博士生导师

• 2015年       俄罗斯米宁大学访学

 主持项目

1. “非对称β-二亚胺稀土金属配合物的合成及性能研究”，国家自然科学基金面上项目(22171003)，60万元，2022.1-2025.12，主持
   

2. “噻吩基稀土金属烷基和胺基化合物的合成及应用研究”，国家自然科学基金面上项目(21672003)，65万元，2017.1-2020.12，主持

3. “稀土金属胺化物与亚胺基、胺基取代吲哚反应性研究及应用”，国家自然科学基金青年项目(21202002)，25万元，2012.1-2015.12，主持 

4. “稀土胺基配合物与含胺基、亚胺基吲哚化合物的C-H键活化反应研究”，安徽省教育厅重点项目（KJ2012A138），3.5万，  2012.1-2013.12, 主持

5. 安徽师范大学博士科研启动基金，2万元，主持

6. “硅桥联芳胺基稀土配合物合成及催化活性研究”，安徽师范大学科研培育基金项目 0.8万，2011.1-2013.12，主持

  研究领域

1. 金属有机化学

2. 有机合成

  讲授课程

1. 有机化学

2. 药物化学

3. 基础/综合化学实验

 代表性论文

1. Dianjun Guo, Dongjing Hong, Zeming Huang, Shuangliu Zhou, Xiancui Zhu,* Shaowu Wang*. “Reactivity of Rare-Earth Metal Alkyl Complexes with Nitriles or Isonitrile: Versatile Ways toward Multiple Functionalized β-Diketiminato, (Iso)indolyl and Imidazolyl Chelating Rare-Earth Metal Complexes”, Inorg. Chem., 2024, 63, 9539–9551.

2. Xiancui Zhu,*^, Jinrong Sun, Zhixin Wu, Dianjun Guo, Shuangliu Zhou, Shaowu Wang*,“Anti-Markovnikov Hydroamination and Hydroalkoxylation of Allylic Alcohols Promoted by a Simple Rare-Earth Metal Trialkyl Complex”, Adv. Synth. Catal., 2024, 366, 1405–1411.

3. Haiyan Zou, Ziqian Wang, Dianjun Guo, Lijun Zhang, Shaowu Wang, Xiancui Zhu*,“Synthesis and catalytic activity of tetradentate β-diketiminato rare-earth metal monoalkyl complexes in tandem Oppenauer oxidation and cross-aldol condensation”, Dalton Trans., 2024, 53, 267–275.

4. Dianjun Guo, Thayalan Rajeshkumar, Shan Zhu, Qingbing Yuan, Dongjing Hong, Shuangliu Zhou, Xiancui Zhu,* Laurent Maron,* Shaowu Wang*,“Aryl C–H bond functionalization with diphenyldiazomethane induced by rare-earth metal alkyl complexes”, Dalton Trans., 2023, 52, 11315–11324.

5. Xiancui Zhu,* Jinqiang He, Yuanqing Yang, Shuangliu Zhou,* Yun Wei, Shaowu Wang. “Synthesis of rare-earth metal complexes with a morpholine-functionalized β-diketiminato ligand and their catalytic activities towards C–O and C–N bond formation”, Dalton Trans., 2022, 51, 13227–13235.

6. Xiancui Zhu,* Yawen Qi, Yuanqing Yang, Dianjun Guo, Zeming Huang, Lijun Zhang, Yun Wei, Shuangliu Zhou, Shaowu Wang*. “Rare-Earth-Metal-Complexes-Catalyzed Hydroalkoxylation and Tandem Hydroalkoxylation/Cyclohydroamination of Isocyanates: Synthesis of Carbamates and Oxazolidinones”, Inorg. Chem. 2022, 61, 3202–3211.

7. Xiancui Zhu,* Ziqian Wang, Ling Zha, Yiwei Zhang, Yawen Qi, Qingbing Yuan, Shuangliu Zhou, Shaowu Wang*. “Synthesis and Characterization of N,N,C and N,N,O Tridentate β-Diketiminato Rare-Earth Metal Alkyl Complexes and Their Catalytic Performances on the Dimerization of Aldehydes or Terminal Alkynes”, Organometallics 2022, 41, 1087−1098.

8. Xiancui Zhu, Dianjun Guo, Fangshi Yao, Zeming Huang, Yang Li, Zuowei Xie, and Shaowu Wang*. “Synthesis, Characterization, and Catalytic Activity of Dinuclear Rare-Earth Metal Alkyl Complexes Bearing 2,6-Diisopropylphenylamidomethyl Fuctionalized Pyrrolyl Ligand”, Organometallics 2021, 40, 1633−1641.

9. Xiancui Zhu,* Mengchen Xu, Jinrong Sun, Dianjun Guo, Yiwei Zhang, Shuangliu Zhou, and Shaowu Wang*.“Hydroamination and Hydrophosphination of Isocyanates/Isothiocyanates under Catalyst-Free Conditions”, Eur. J. Org. Chem. 2021, 37, 5213−5218.

10. Xiancui Zhu,* Dianjun Guo, Zeming Huang, Tian Sheng,* Shaowu Wang,* Mengke Pan, Ling Zha, Shuangliu, Zhou, “Dehydrogenative Coupling of Terminal Alkynes with O/N-Based Monohydrosilanes Catalyzed by Rare-Earth Metal Complexes”, Inorg. Chem. 2020, 59, 14152–14161.

11. Xiancui Zhu,* Dianjun Guo, Yiwei Zhang, Yun Wei, Shuangliu Zhou, Mengchen Xu, Shaowu Wang,* Yuanqing Yang, Yawen Qi. “Synthesis of Carbamoylphosphates from Isocyanates Catalyzed by Rare-Earth Metal Alkyl Complexes with a Silicon-Linked Diarylamido Ligand”, Organometallics 2020, 39, 4584–4591.

12. Xiancui Zhu, Yuzhe Jiang, Jun Chen, Shaowu Wang,* Zeming Huang, Shan Zhu, Xu Zhao, Wenrun Yue, Jun Zhang, Weikang Wu, Xiangyang Zhong, “Rare-Earth Metal Alkyl Complexes with 3-Arylamido-Functionalized Indolyl Ligands: Synthesis, Characterization and Reactivity”, Chin. J. Chem. 2020, 38, 478–488.

13. Xiancui Zhu,* Yang Li, Dianjun Guo, Shaowu Wang,* Yun Wei, Shuangliu Zhou, “Versatile reactivities of rare-earth metal dialkyl complexes supported by a neutral pyrrolyl functionalized β-diketiminato ligand”, Dalton Trans.2018, 47, 3947–3957.

14. Xiancui Zhu,* Yang Li, Yun Wei, Shaowu Wang,* Shuangliu Zhou, Lijun Zhang,“Reactivity of 3-imino-functionalized indoles with rare-earth-metal amides:unexpected substitutent effects on C-H activation pathways and assembly of rare-earth-metal complexes”, Organometallics 2016, 35, 1838–1846.

15. Xiancui Zhu, Shuangliu Zhou, Shaowu Wang,* Yun Wei, Lijun Zhang, Fenhua Wang, Shaoyin Wang, Zhijun Feng, “Rare-earth metal complexes having an unusual indolyl-1,2-dianion through C-H activation with a novel η¹:(µ₂-η¹:η¹) bonding with metals”, Chem Commun. 2012, 48, 12020–12022.

16. Xiancui Zhu, Shaowu Wang,* Shuangliu Zhou, Yun Wei, Lijun Zhang, Fenhua Wang, Zhijun Feng, Liping Guo, and Xiaolong Mu, “Lanthanide Amido Complexes Incorporating Amino-Coordinate-Lithium Bridged Bis(indolyl) Ligands: Synthesis, Characterization, and Catalysis for Hydrophosphonylation of Aldehydes and Aldimines”, Inorg. Chem. 2012, 51, 7134–7143.

17. Dongjing Hong, Xiancui Zhu,* Shaowu Wang, * Yun Wei, Shuangliu Zhou, Zeming Huang, Shan Zhu, Ruru Wang, Wenrun Yue and Xiaolong Mu. “Synthesis, characterization, and reactivity of dinuclear organo-rare-earth-metal alkyl complexes supported by 2-amidate-functionalized indolyl ligands: substituent effects on coordination and reactivity”, Dalton Trans. 2019, 48, 5230–5242.

18. Zeming Huang, Shaowu Wang,* Xiancui Zhu, Qingbing Yuan, Yun Wei, Shuangliu Zhou, and Xiaolong Mu, “Well-Defined Amidate-Functionalized N‑Heterocyclic Carbene-Supported Rare-Earth Metal Complexes as Catalysts for Efficient Hydroboration of Unactivated Imines and Nitriles”, Inorg. Chem. 2018, 57, 15069–15078.

19. Guangchao Zhang, Shaowu Wang,* Xiancui Zhu, Shuangliu Zhou, Yun Wei, Zeming Huang, and Xiaolong Mu. Organometallics 2017, 36, 3812–3822.

20. Guangchao Zhang, Baojia Deng, Shaowu Wang,* Yun Wei, Shuangliu Zhou, Xiancui Zhu, Zeming Huang and Xiaolong Mu, “Di and trinuclear rare-earth metal complexes supported by 3-amido appended indolyl ligands: synthesis, characterization and catalytic activity towards isoprene 1,4-cis polymerization”, Dalton Trans. 2016, 45, 15445–15456.

21. Liping Guo, Xiancui Zhu, Guangchao Zhang, Yun Wei, Lixin Ning, Shuangliu Zhou,* Zhijun Feng, Shaowu Wang,* Xiaolong Mu, Jun Chen, Yuzhe Jiang, “Synthesis and Characterization of Organo-Rare-Earth Metal Monoalkyl Complexes Supported by Carbon sigma-Bonded Indolyl Ligands: High Specific Isoprene 1,4-Cis Polymerization Catalysts”, Inorg. Chem. 2015, 54, 5725–5731.

22. Qingbing Yuan, Shuangliu Zhou,* Xiancui Zhu, Yun Wei, Shaowu Wang,* Xiaolong Mu, Fangshi Yao, Guangchao Zhang and Zheng Chen, “ Heterometallic rare-earth metal complexes with imino-functionalized 8-hydroxyquinolyl ligands: synthesis, characterization and catalytic activity towards hydrophosphinylation of trans-nitroalkene”, New J. Chem. 2015, 39, 7626–7632.

23. Guangchao Zhang, Yun Wei, Liping Guo, Xiancui Zhu, Shaowu Wang,* Shuangliu Zhou, Xiaolong Mu,“Dinuclear Rare-Earth Metal Alkyl Complexes Supported by Indolyl Ligands in µ-η²:η¹:η¹ Hapticities and their High Catalytic Activity for Isoprene 1,4-cis-Polymerization”, Chem. Eur. J. 2015, 21, 2519–2526.

24. Xiaoxia Gu, Lijun Zhang, Xiancui Zhu, Shaowu Wang,* Shuangliu Zhou, Yun Wei, Guangchao Zhang, Xiaolong Mu, Zeming Huang, Dongjing Hong, and Feng Zhang, “Synthesis of Bis(NHC)-Based CNC-Pincer Rare-Earth-Metal Amido Complexes and Their Application for the Hydrophosphination of Heterocumulenes”, Organometallics 2015, 34, 4553–4559.

25. Fenhua Wang, Yun Wei, ShaowuWang,* Xiancui Zhu, Shuangliu Zhou, Gaosheng Yang, Xiaoxia Gu, Guangchao Zhang, Xiaolong Mu, “Synthesis, Characterization, and Reactivity of Lanthanide Amides Incorporating Neutral Pyrrole Ligand. Isolation and Characterization of Active Catalyst for Cyanosilylation of Ketones”, Organometallics 2015, 34, 86–93.

26. Zhijun Feng, Yun Wei, Shuangliu Zhou, Guangchao Zhang, Xiancui Zhu, Liping Guo, Shaowu Wang* and Xiaolong Mu,“Reactivity of functionalized indoles with rare-earth metal amides. Synthesis, characterization and catalytic activity of rare-earth metal complexes incorporating indolyl ligands”, Dalton Trans. 2015, 44, 20502–20513.

27. Song Yang, Xiancui Zhu,* Shuangliu Zhou, Shaowu Wang,* Zhijun Feng, Yun Wei, Hui Miao, Liping Guo, Fenhua Wang, Guangchao Zhang, Xiaoxia Gu and Xiaolong Mu, “Synthesis, structure and catalytic activity of rare-earth metal amides with a neutral pyrrolyl-functionalized indolyl ligands”, Sci. China. Chem. 2014, 57, 1090–1097.

28. Xiaoxia Gu, Xiancui Zhu,* Yun Wei, Shaowu Wang,* Shuangliu Zhou, Guangchao Zhang, and Xiaolong Mu, “CNC-Pincer Rare-Earth Metal Amido Complexes with a Diarylamido Linked Biscarbene Ligand: Synthesis, Characterization, and Catalytic Activity”, Organometallics 2014, 33, 2372–2379.